By Janice Smith, Erin Smith Berk
Written by means of Janice Gorzynski Smith and Erin R. Smith, the coed examine Guide/Solutions handbook offers step by step recommendations to all in-chapter and end-of-chapter difficulties. every one bankruptcy starts with an summary of key thoughts and contains key ideas and precis tables.
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CH3)3O+ e. CH3 C C H 4 groups (3 atoms, 1 lone pair) sp3, tetrahedral d. CH2Cl 4 groups (4 atoms) sp3, tetrahedral 2 groups (2 atoms) sp, linear f. CH2=NOCH3 3 groups (2 atoms, 1 lone pair) sp2, trigonal planar g. CH3CH=C=CH2 3 groups (3 atoms) sp2 trigonal planar 2 groups (2 atoms) sp, linear Smith: Study Guide/ Solutions Manual to accompany Organic Chemistry, Third Edition 1. 29. O Csp2–Csp3 H H : Csp2–Osp2 : Cp–Op Csp3–H1s a. c. Csp3–Csp3 Csp–Csp2 : Csp2–Csp2 : Cp–Cp H Csp2–H1s b. H C C C N CH3 d.
CH3)2CHOH + Li+ –N[CH(CH3)2]2 acid base + HN[CH(CH3)2]2 conjugate base (CH3)2CHOH2 + conjugate acid conjugate acid –OCOCH 3 conjugate base To cross a cell membrane, amphetamine must be in its neutral (not ionic) form. CH3 CH2 CH3 protonation CH2 C H C H NH2 by HCl in the stomach NH2 CH3 deprotonation CH2 C H in the intestines H amphetamine NH2 absorption here in the neutral form Lewis bases are electron pair donors: they contain a lone pair or a bond. a. 29 propranolol OH Draw the products of proton transfer from the acid to the base.
Csp3–Csp3 Csp–Csp2 : Csp2–Csp2 : Cp–Cp H Csp2–H1s b. H C C C N CH3 d. 29. Csp3–Osp3 Osp3–H1s H a. : Csp2–Osp2 : Cp–Op O Csp3–Osp3 CO2H O O O b. 73 CH2 CH sp2 sp : Csp2–Csp : Cp–Cp CH2 CH sp2 sp2 : Csp2–Csp2 : Cp–Cp C 27 28 Smith: Study Guide/ 1. 34. H H a. C C H C C H H H H C C CH2 C C C H H H H H double bond middle triple bond shortest b. 34. a. HO NH2 b. ) Cl Br c. 76 c. shortest, strongest C–C bond b. and d. bond (1) longest, weakest C–C bond (2) single bond H a. shortest C–C single bond e.
Study Guide/Solutions Manual for Organic Chemistry by Janice Smith, Erin Smith Berk