By Jie Jack Li, E. J. Corey
This sensible, well-organized reference delves deeply into useful staff modifications, to supply the entire precise info that researchers need.* issues are prepared into the next sections: oxidation, aid, uneven synthesis, and useful team manipulations * each one part encompasses a description of the practical team transformation, the ancient viewpoint, mechanisms, adaptations and enhancements at the response, artificial utilities and purposes for the response, experimental info, and references to the first literature * participants are famous and revered for his or her paintings at the particular identify reactions.
Quality: nice experiment, Searchable, no longer bookmarked
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J. Org. Chem. 1984, 49, 1316. Midland, M. ; Gabriel, J. J. Org. Chem. 1989,54, 159. Midland, M. ; Lee, P. E. J. Am. Chem. 1985,107,3237. Brown, J. ; Pai, G. ; Jadhav, P. K. JAm. Chem. 1984, 106,1531. Johnson, W. ; Gopalan, A. S. J. Org. Chem. 1981,46, 1512. ; Kalvin, D. ; Woodard, R. W. Tetrahedron, 1988,44,5597. Ready, M. V. ; Rearick J. ; Rarnachandran, P V. 2001,3, 19. ; Sulikowski, G. A. Org. Lett. 2005, 7, 5163. Julia M. 2 Homogeneous catalytic asymmetric hydrogenation has become one of the most efficient methods for the synthesis of chiral alcohols, amines, a-and p-amino acids, and many other important chiral intermediates.
Reddy, R. ; Carroll, P. J. Org. Chem. 1997,62,2555-63. -C. J. Org. Chem. 1991,56, 1143-5. Richard J. Mullins and Michael T. 1 Description The Midland reduction is the enantioselective reduction of a ketone (1 to an optically active alcohol (2) using the commercially available reagent alpine borane (3). * (+ room temperature 6a ? 0""" 7a 100'C R= n-alkyl Extension of this methodology to an enantioselective variant soon followed. 3 Mechanism and Stereochemical Rationalization Initial debate over the mechanism of the Midland reduction centered around the idea that this reduction could reasonably proceed via either a one-step (Path A) or two-step (Path B) mechanism as shown below.
Name Reactions of Functional Group Transformations by Jie Jack Li, E. J. Corey