By Pher G. Andersson
C-H, C-O, C-C, and C-Heteroatom bond forming methods through the use of metal-ligand techniques for the synthesis of natural compounds of
biological, pharmacological and natural nanotechnological software are the main parts addressed during this publication. Authored via a ecu team
of leaders within the box, it brings jointly cutting edge methods for numerous catalysis reactions and procedures often utilized in organic
synthesis right into a convenient reference paintings. It covers all significant varieties of catalysis, together with homogeneous, heterogeneous, and organocatalysis, as
well as mechanistic and computational experiences. specified cognizance is paid to the advancements in potency and sustainability of important
catalytic tactics, reminiscent of selective oxidations, hydrogenation, and cross-coupling reactions, and to their usage in industry.
The result's a worthwhile source for complicated researchers in either academia and undefined, in addition to graduate scholars in natural chemistry
aiming for chemo-, regio- or stereoselective synthesis of natural compounds by utilizing novel catalytic systems.
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Additional info for Innovative Catalysis in Organic Synthesis: Oxidation, Hydrogenation, and C-X Bond Forming Reactions
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15). 15 Alkane hydroxylation using [Fe(II)(bpbp)(CH3 CN)2 ](SbF6 )2 . (a) Substrate electronic effects on site selectivity in the hydroxylation of substrates with various tertiary C–H bonds. (b) Selective hydroxylation based on steric effects. 16 catalyst. H yield = 53% CH3CN Steric crowding O O Electronically deactivated chain H H yield = 28% Selective methylene oxidation with the [Fe(II)(bpbp)(CH3 CN)2 ](SbF6 )2 on the basis of the electronic and steric properties of the C–H bonds. In addition, this methodology could be impressively employed in the hydroxylation of complex natural products .
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Innovative Catalysis in Organic Synthesis: Oxidation, Hydrogenation, and C-X Bond Forming Reactions by Pher G. Andersson