Read e-book online Electrochemistry - Electroorganic Synthesis Bond Formation PDF

By E. Steckhan, R.D. Little, K.D. Moeller, J.-Y. Nedelec, J. Perichon, M.K. Schwaebe, I. Tabakovic, M. Troupel

ISBN-10: 3540614540

ISBN-13: 9783540614548

The quantity Electrochemistry VI of subject matters in present Chemistry is subtitled Electroorganic Synthesis: Bond Formations on the Anode and Cathode. It highlights either the present price and the massive strength of natural electrochemistry for the selective formation of carbon-carbon and carbon-heteroatom bonds and for the new release of complicated natural molecules utilizing electrochemical key steps. The contents variety from the synthesis of typical items to the training of prescribed drugs, from the new release of unsymmetrical biaryls to the development of peptide mimetics. the professionals and cons of the electroorganic method compared to replacement tools are mentioned and mechanistic issues are integrated. specialists of their fields current fresh effects.

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Additional resources for Electrochemistry - Electroorganic Synthesis Bond Formation at Anode and Cathode

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5 Direct Intramoleeular Carbon-Carbon Bond Forming Reactions . . 1 Coupling Reactions Involving Aryl Rings and Olefins . . . . 2 Intramolecular Anodic Olefin Coupling Reactions . . . . . 53 55 55 57 58 63 63 64 66 66 76 6 Conclusions . . . . . . . . . . . . . . . . . . 83 7 References . . . . . . . . . . . . . . . . . . 84 Topics in Current Chemistry, Vol. D. The transformationsexaminedrange from fragmentation reactions resulting in radical cyclization pathways to radical cation-based cycloaddition reactions resulting in the formation of two or more bonds.

83 7 References . . . . . . . . . . . . . . . . . . 84 Topics in Current Chemistry, Vol. D. The transformationsexaminedrange from fragmentation reactions resulting in radical cyclization pathways to radical cation-based cycloaddition reactions resulting in the formation of two or more bonds. The products generated range from simple five-,six-,and seven-memberedrings to complexbridged and fusedpolycyclicring skeletons. Many of the cyclicproducts obtained either retain the functionalityused to intitiate their formation or have a higher level of functionality than that found in the starting material.

Snider and Kwan have demonstrated that the oxidation of silyl enol ethers derived from phenyl ketones with either Cu(II) or Ce(IV) salts can lead to efficient cyclization reactions [4]. However, related cyctization reactions starting with silyl enol ethers derived from dialkyl ketones proceeded in much lower yields. In priniciple, anodic electrochemistry can provide a single method for oxidizing all of these substrates. However, there are still many questions to be answered before electrochemistry can be claimed as a success in this area.

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Electrochemistry - Electroorganic Synthesis Bond Formation at Anode and Cathode by E. Steckhan, R.D. Little, K.D. Moeller, J.-Y. Nedelec, J. Perichon, M.K. Schwaebe, I. Tabakovic, M. Troupel


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