By Samuel Glasstone
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Additional resources for An introduction to electrochemistry
And C g should be repeated and the bridge again balanced. 17. of consists , , , D . C. Bridge. In order to eliminate the electrostatic on one another, and also that due influence between parts of the bridge * This adjustment includes that of a condenser (not shown) in above; see also page 33 and Fig. 9. parallel, as explained PREPARATION OF SOLVENT 43 to outside disturbances, grounded metallic shields have sometimes been placed between the various parts of the bridge, or the latter has been completely surrounded by such shields.
Anodes of iron, lead and tin almost invariably dissolve in the lower valence state. Similar arguments to those given above will apply to the deposition at the cathodo; the proportion in which the higher and lower valence ions are discharged is identical with that in which an anode would dissolve in the same electrolyte. , from a solution of the perchlorates or nitrates, the two ions would be discharged in the ratio of 120 to unity. }'. Since the discharge at a cathode or Significance of Faraday's Laws.
The cells for electrolytic conductance measurements are made of highly insoluble glass, such as Pyrex, or of quartz; they should be very carefully washed and steamed before use. For general laboratory requirements the simple cell designed by Ostwald (Fig. 12, I)' is often employed, but for industrial purposes the "dipping cell" (Fig. 12, II) or the pipette- type of cell (Fig. 12, III) have been found convenient. By means of the two latter cells, samples obtained at various stages in a chemical process can be readily tested.
An introduction to electrochemistry by Samuel Glasstone