J. D. Dunitz's Alkali Metal Complexes with Organic Ligands PDF

By J. D. Dunitz

Content material: Molecular modelling and bonding / Elaine Moore -- Case research : Molecular modelling in rational drug layout / man provide and Elaine Moore

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Paths containing the smallest number of cyclization steps (which may require special conditions, see below) are preferable, provided only one ring is formed per step. Paths a, b, and c in Figure 4 each contain two cyclization steps (first and third steps) ; paths d and e each contain three such steps. 8. Stepwise syntheses provide intermediate structures which may also have interesting ligand properties. Macrocycle Formation Special synthetic problems in the elaboration of ligands of type A--0r are connected with their macrocyclic nature.

3 -- -- TI+ (28) (127) (127) (28) (28) (127) (708) (127) (83) (28) (127) (28) (28) (127) Ref. Table 9. Stability constants (log Ke) of alkali and alkaline-earth metal cation complexes with ligands o] lype G and J (Ks in lmol -x at 25 ~ "t Design of Organic Complexing Agents. -M. Lehn T a b l e lO. Stability constants (log K~) o/alkali and alkaline-earth metal cation com- plexes with some selected natural antibiotic ligands (1s in lmo1-1) Substance SolTemv e n t a) perature log Ks w i t h cation Ref.

5 . 5 . 0 . Baa+ . . . -- -- -- -- . 6 . 6 -- Ag + . . -- - -- . 3 -- -- TI+ (28) (127) (127) (28) (28) (127) (708) (127) (83) (28) (127) (28) (28) (127) Ref. Table 9. Stability constants (log Ke) of alkali and alkaline-earth metal cation complexes with ligands o] lype G and J (Ks in lmol -x at 25 ~ "t Design of Organic Complexing Agents. -M. Lehn T a b l e lO. Stability constants (log K~) o/alkali and alkaline-earth metal cation com- plexes with some selected natural antibiotic ligands (1s in lmo1-1) Substance SolTemv e n t a) perature log Ks w i t h cation Ref.

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Alkali Metal Complexes with Organic Ligands by J. D. Dunitz


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